Currently the Hybrid Config Wizard is unable to accept accounts which are protected by Azure MFA, including app passwords.
Please allow the use of MFA in the Hybrid Config Wizard so we can protect all elevated access accounts in O365.24 votes
I am happy to announce that the MFA for SharePoint Hybrid is now available for anyone to use. You can download the latest version of the SharePoint hybrid configuration Wizard and use it with MFA. https://go.microsoft.com/fwlink/?linkid=867176
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